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NH3 Gas Sensor

Ammonia Sensors and Detection

Ammonia gas is a chemical compound comprised of one nitrogen and three hydrogen atoms, commonly referred to as the ammonia molecule with the formula NH3. In its pure form, ammonia is a colorless gas, but it is easily identifiable by its pungent odor. Ammonia is normally found as a gas, which is caustic and harmful with prolonged exposure, requiring a hazardous safety permit. 

Ammonia gas detectors with nh3 sensors help workers in multiple industries determine the range of gas they are exposed to in real-time.

Connected gas detectors like the Blackline G8 go beyond showing the range of gas on a device display; they also operate as an automatic alarm system when a sensor detects dangerous levels, and will send a help alert for a worker that might not be able to do so themselves. All of the data recorded via the device sensor is accessible in real time to safety teams, and incidents are logged automatically when they occur. 

Ammonia gas is commonly produced in the manufacturing of fertilizers, refrigerants, and cleaning solutions, or in agricultural settings, like poultry farms. Unlike some other gases that pose risks to workers, you are likely to smell ammonia well before it enters a harmful range. The degree of danger that it poses varies significantly depending on how much is present, and how long you've been exposed. Monitoring ammonia gas levels with real time readings is crucial to prevent potential health risks.

Industrial ammonia production is one of the highest for inorganic chemicals, with numerous large-scale fertilizer plants and other facilities producing 235 million tons of ammonia in 2021. Ammonia is produced industrially through the Haber-Bosch process, which combines nitrogen from the air with hydrogen, typically derived from natural gas, under high pressure and temperature in the presence of a catalyst.

Ammonia Toxicity:
Exposure to high ammonia concentrations can be harmful to human health. Inhalation of ammonia gas can irritate the respiratory tract, causing coughing, wheezing, and difficulty breathing. In severe cases, it can lead to pulmonary edema, a condition where fluid accumulates in the lungs. A reliable protection system, such as a gas detector equipped with an ammonia (nh3) sensor, will provide visual and audible alerts for high alarm and low alarm presence, to a high degree of accuracy with proper calibration. 

Risk factors of NH3 that require an ammonia gas detector for safe handling:

  • Colorless

  • Gas state

  • Compressed

  • Toxic

  • Flammable

  • Corrosive

  • Lighter than air

  • Water soluble

  • Explosive (at high concentrations and confined spaces)

  • Pungent, suffocating odor

  • Can decompose at high temperatures forming very flammable hydrogen gas

  • Ammonia based fertilizers and agricultural land management can cause emissions of nitrous oxide.

  • Ammonia molecules have a trigonal pyramid shape

  • OTHER NAMES: Anhydrous ammonia, ammonia, azane, hydrogen nitride

  • CAS 7664-41-7

Key benefits of the right sensor for ammonia gas detection:

Ammonia gas detection is critical in many industries, especially in food processing facilities with refrigeration, fertilizer plants, and other facilities handling ammonia. Ammonia sensors and ammonia detectors are essential for fixed and portable gas detection systems, helping to ensure that ammonia concentrations stay within safety regulations.

These systems are designed to provide real-time monitoring, alerting workers to any dangerous gas buildup. Fixed and wearable Ammonia gas detectors, with proper calibration for accurate readings, play a critical role in monitoring ammonia levels in food processing facilities and other commercial and industrial workplaces to ensure a safe and compliant environment, and to protect both workers and consumers.

By using ammonia gas detectors, businesses can reduce the risk of harmful exposure and false alarms, providing a effective solution that ensures worker safety and productivity. 

icon ghs flammable - examples include nitrogen oxides, concentrated ammonia solutions, anhydrous ammonia
icon ghs toxic - examples include nitric acid which can dissolve alkali metals and cause harm to the respiratory tract of workers along with ammonium chloride
icon-ghs-compressed-gas-or-compressed-liquid
GHS corrosive WHMIS - examples include sulphuric and nitric acids including ammonium hydroxide is a corrosive gas

What conditions typically require workers to wear an ammonia detector?

  • Farms:
    In agriculture, ammonia sensors are essential for monitoring air quality in livestock housing and ensuring safe levels of ammonia to protect both worker and animal health. Ammonia produced by compost piles, manure pits and any indoor or confined agriculture operations where farm animals are kept can also contain ammonia gas. Fertilizer stored and used on farms also poses a risk.

  • Water treatment: Ammonia is used to produce monochloramine which is used as a disinfectant in water and wastewater treatment processes.

  • Refrigeration Systems: Ice rinks, breweries, food & beverage manufacturing, cold storage warehouses, and ice manufacturing plants often use liquid ammonia, or aqueous ammonia - NH3(aq). If it leaks, it becomes ammonia gas, resulting in potentially hazardous ammonia emissions.

  • Fertilizers and Cleaners: Liquid ammonia is often diluted and combined with other chemical substances, forming solutions called ammonium hydroxide. This diluted form is used in household cleaning products and as an ingredient in fertilizers, with a potential for ammonia emissions during application, storage, and manufacturing.

  • Ammonium salts may form when ammonia reacts with various acids, impacting both safety and environmental handling measures. Some manufacturing processes combine ammonia with hydrochloric acid to produce ammonium chloride.

  • Workers may be exposed while using cleaning products that contain ammonia.

  • Other sources of occupational exposure include the silvering of mirrors, gluemaking, tanning of leather, and around nitriding furnaces.

  • Ammonia is produced as a by-product in coal distillation and by the action of steam on calcium cyanamide, and from the decomposition of nitrogenous materials.

  • Ammonia is produced naturally in agricultural products including soybeans, evening-primrose seeds, lambs quarter, and tobacco leaves.

Ammonia leaks are on the rise due to increased use of natural refrigerants over fluorinated gas counterparts.

(Process Equipment & Control News)

High Risk Scenarios:

  • Warmer buildings can produce ammonia in higher concentrations than cold buildings.

  • In an enclosed environment, ammonia can explode if an ignition source is introduced.

  • Outside of an accidental release of ammonia, the potential for exposure to high concentrations of ammonia is greatest during confined space entry.

  • Technically speaking, the moment a worker breaks the plane of an opening, he or she has in fact entered a confined space, and when ammonia is involved, workers should assume that confined spaces present a hazardous environment.

  • In the event of a leak or CSE procedure, it would be a mistake to assume that ammonia’s distinct odor would serve as an adequate warning signal. An accurate sensor is essential to determining danger.

  • Ammonia gas detectors with the correct sensor calibration can measure the concentrations of ammonia and quickly alert workers of changes in air quality.

NH3 Sensor Info

Type: Electrochemical
Range: 0-100 ppm (0.1 ppm resolution)
High Range: 0-500 ppm (1 ppm resolution)

Default Alarm Levels

Low Alarm: 25 ppm
High Alarm: 50 ppm
STEL — 15 minute — Short Term Exposure Limit: 35 ppm 
TWA  — 8 hour time weighted average: 25 ppm 

Questions about the detection of NH3?

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Other environmental conditions where ammonia (NH3) may be present:

  • Slow-moving water: Slow-moving or stagnant water may have high ammonia gas concentrations because of lack of turbulence and volatilization and greater accumulation of metabolic waste and decomposition products—including ammonia (WHO 1986).
  • High density of fish: Reduced stream flow may concentrate fish into pools or other refugia, concentrating waste excretion and elevating ammonia concentrations.
  • Presence in organic wastes: Organic wastes are the remains of any once-living organism or their excrement. Ammonia excretion from the body also occurs through urine so the average concentration in domestic sewage influent is 40 mg/L. Identifying the organic matter in waterbodies or aqueous solutions aids in identifying the source.
      – Ammonia levels in water <1 mg/L can be harmful.
  • Plant material is typically low in nitrogen, and associated decomposers may take up ammonia and reduce its aqueous concentration. Identifying the type of organic waste present in a waterbody will aid in identifying candidate causes. Excessive organic wastes in water may result in a grayish cast with visible sludge deposits in depositional areas.
  • Foul odor: Ammonia gas has a characteristically pungent odor (think of window and floor cleaners). Ammonia concentrations in streams are rarely high enough to exhibit this odor, but water that has a foul, septic or organic-waste smell may have relatively high concentrations of ammonia.
  • Suspended solids: Suspended solids from wastewater effluents or runoff can contain high ammonia or act as catalysts for bacterial growth promoting accumulation of ammonia. Identifying the type of suspended material present is important in identifying candidate causes.
  • Alkaline, anoxic, or warm water: Water characteristics that promote ammonia formation (e.g., anoxia) or increase toxicity (e.g., high pH and temperature) are signs that ammonia may be a cause.
  • Ammonia solution also known as aqueous ammonia is ammonia diluted in water. It serves various purposes from being an ingredient in household cleaners, disinfectant for water treatment, food production to bring down the acidity in food, and even furniture darkening.
  • Medical uses: ammonia is being used as a respiratory stimulant to prevent fainting, commonly known as smelling salts

Health Risks and Handling of NH3

concentration
symptoms/effects
0 - 0.5 ppm
Typical background levels of low concentrations.
0.6 - 23 ppm
Still considered a low concentration but can usually be detected by smell.
24 - 29 ppm
Nose and throat irritation can occasionally be detected (2-6 hours of exposure)
30 - 49 ppm
Slightly irritating to some people after 10 minutes of exposure
50 - 71 ppm
Moderately irritating to the majority of people after 10 minutes of exposure
72 - 139 ppm
Continuous exposure to NH3 can cause irritation of the nose and throat after only 5 minutes.
140 - 499 ppm
Will be unbearably irritating to most people after 30 minutes
500 - 1499 ppm
Nose and throat will immediately experience severe irritation, lacrimation occurs (crying)
1500 - 2499 ppm
Brief exposure can lead to a pulmonary edema (accumulation of fluid in the lungs, potentially fatal)
2500 - 4500 ppm
Death likely after 30+ minutes of exposure
5000ppm +
Will often cause rapid respiratory arrest, death very likely
NH3 first aid
FIRST AID
  • Inhalation: Take precautions to ensure your own safety before attempting rescue (e.g., wear appropriate protective equipment). Move victim to fresh air. If breathing is difficult, trained personnel should administer emergency oxygen. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary edema may be delayed. Immediately call a Poison Centre or doctor. Treatment is urgently required. Transport to a hospital.
  • Skin Contact from Gas: flush with lukewarm, gently flowing water for 5 minutes. If irritation or pain persists, see a doctor. 
  • Eye Contact from Gas: immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes, while holding the eyelid(s) open. If irritation or pain persists, see a doctor. 
NH3 dangers
IF ACCIDENTALLY RELEASED
  • Handling: Immediately report leaks, spills, or failures of the safety equipment (e.g., ventilation system). In event of a spill or leak, immediately put on escape-type respirator and exit the area. Do NOT work alone with this product. Get medical attention for all exposures. Symptoms can be delayed. Prevent accidental contact with incompatible chemicals.

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